ER (Lithium Thionyl Chloride Battery)

ER (Lithium Thionyl Chloride Battery)

 

Product Information

Overview

This battery is ideal for such long-term applications as power for electronic devices and electric power, water, and gas meters, and especially as a backup power source for memory ICs.

Features

•High 3.6-V voltage
The lithium thionyl chloride battery achieves a high voltage of 3.6 V.

•Flat discharge characteristics
The change of internal resistance during discharge is minimal, allowing for flat discharge voltage until end of discharge life.

•High energy density
Provides high energy density of 970m Wh/cm3 with discharge current of 100 µA (ER6 type).

•Wide usable temperature range
Can be used over a wide temperature range : - 55 deg. C to +85 deg. C (please consult with Maxell
if using in temperatures of -40 deg. C or less).

•Superior long-term reliability
The extremely low self-discharge, together with the use of a hermetic seal, allows for stable use
over long periods.

•UL (Underwriters Laboratories Inc.) recognized component

Product list

Model Nominal Voltage (V) Nominal Capacity (mAh)*2 Nominal Discharge Current (µA) Operating
Temperature
Range
(deg. C)
Dimensions*1
Weight (g)*1 Data Sheets With
terminals
Warnings
Diameter (mm) Height (mm)
ER18/50 3.6 3,650 125 -55 to +85 18 52.6 22 pdf
456KB
pdf
464KB
pdf
792KB
ER17/50 3.6 2,750 125 17 52.6 20 pdf
520KB
pdf
416KB
ER6 3.6 2,000 100 14.5 53.5 15 pdf
520KB
pdf
416KB
ER6C 3.6 1,800 100 14.5 51 15 pdf
520KB
pdf
432KB
ER17/33 3.6 1,600 75 17 35 13 pdf
520KB
pdf
432KB
ER3 3.6 1,100 40 14.5 29.9 8 pdf
496KB
pdf
464KB
ER3S 3.6 790 35 14.5 26 7 pdf
448KB
pdf
464KB

*1 Dimensions and weight are for the battery itself, but may vary depending on the shape of terminals or other factors.
*2 Nominal capacity indicates duration until the voltage drops down to 3.0V when discharged at a nominal discharge current at 20 deg. C.

Maxell ER (lithium thionyl chloride) batteries are available only for equipment manufacturers as a built-in part. Therefore, Maxell does not supply these batteries for replacement directly to users of equipment with these batteries. When built-in ER batteries need to be replaced, please contact your equipment manufacturer. If you are planning to use Maxell ER batteries in your equipment as a built-in part, please contact Maxell.

Maxell ER batteries are not general use products. Improper usage may cause not only poor performance but it may also damage the equipment and/or the human body. Therefore, Maxell sells ER batteries only after confirmation of the usage conditions and scope of warranty within the specifications sheet. Maxell does not guarantee the performance and quality of batteries purchased without agreement of the specifications sheet.

Construction

Principle and Reactions

The lithium thionyl chloride battery uses liquid thionyl chloride (SOCL2) as its positive active material, and lithium (Li) as its negative active material. The reactions of the battery are shown below.

Battery Reactions
Positive reaction : 2SOCl2+4Li++4e-  ->  4LiCl+S+SO2
Negative reaction : Li                   ->  Li++e-
Total reaction : 2SOCl2+4Li         ->  4LiCl+S+SO2

Minimum Transient Voltage

The lithium thionyl chloride battery has remarkably lower self-discharge when compared with conventional batteries. This is because a lithium chloride membrane is formed over the negative lithium surface, blocking reaction with the positive material. When first discharging after storage, resistance from this lithium chloride membrane may temporarily reduce the voltage at the initiation of discharge. The lowest voltage at this time is called minimum transient voltage, and the lower the temperature, and the larger the discharge current, the lower the voltage will be. Because minimum transient voltage is greatly influenced by storage time and conditions, it is necessary to take this into sufficient consideration when designing a device.

The figure above shows minimum transient voltage using a fresh battery.

Relationship between Discharge Load and Operating Voltage

The operating voltage of a battery falls as the discharge load increases and temperature falls. In the case of initial use, an electric potential of at least 3 V will be maintained even at temperatures of -40 deg. C at discharge of less than 1 mA.

Storage Characteristics

The lithium thionyl chloride battery is made from chemically stable inorganic materials. Additionally, a sealing method employing a laser-welded seal structure and hermetic seal hinders the admittance of outside air. These features provide superior storage characteristics, holding down self-discharge to no more than 1% of capacity per year at normal temperatures.

UL Recognized Components

The lithium thionyl chloride battery is a UL (Underwriters Laboratories Inc.) recognized component.
(Technician replaceable)

Recognized models: ER18/50, ER17/50, ER6, ER6C, ER17/33, ER3, ER3S
Certification number: MH12568

Applications

●OA Machines (Fax, Copiers, Printers)
●Desktop PCs ●PDAs
●Medical Instruments, Cash Registers
●FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors)
●Electronic Meters (Gas, Water, Electricity)
●ETC (Electronic Toll Collection System)

 

• Data and dimensions are not guaranteed. For further details, please contact us at your nearest Maxell office.
• Contents on this website are subject to change without notice.

Q1: Primary battery

A1:

Source of electrical energy obtained by the direct conversion of chemical energy and not designed to be charged by any other electrical source.

Q2: Rechargeable battery (Secondary battery)

A2:

Source of electrical energy obtained by the direct conversion of chemical energy designed to be charged by any other electrical source. It is also called a storage battery or accumulator.

Q3: Open circuit voltage (OCV)

A3:

Voltage across the terminals of a battery when no external current is flowing.

Q4: Closed circuit voltage (CCV)

A4:

Voltage across the terminals of a battery when it is on discharge.
As a battery has an internal resistance, CCV is lower than OCV and CCV becomes lower with a range of current.

Q5: Nominal voltage

A5:

Suitable approximate value of voltage used to identify the voltage of a battery.
For example) Alkaline manganese battery; 1.5V
Lithium manganese dioxide battery; 3.0V

Q6: Load

A6:

External device or method through which a battery is discharged.

Q7: End-point voltage (End voltage, Cutoff voltage, Final voltage)

A7:

Specified closed circuit voltage at which a service output test is terminated.

Q8: Internal resistance

A8:

Resistant component in a battery that makes discharge reaction slow.

Q9: Discharge

A9:

Operation during which a battery delivers current to an external circuit.

Q10: Over discharge

A10:

Continue to discharge after a battery voltage drops below its end-point voltage.

Q11: Self discharge

A11:

Decreasing capacity during storage without load, caused by chemical reaction in a battery. The higher the temperature during storage, the greater the rate of self discharge.

Q12: Discharge characteristics (Discharge curve)

A12:

Change of a battery voltage with discharge.

Q13: Charge

A13:

Operation during which a reverse reaction of discharge occurs when electrical energy is received from an external source.

Q14: Polarization

A14:

Voltage deviation from equilibrium caused by charge or discharge.

Q15: Duration time (Duration period)

A15:

Time until a battery voltage exceeds the end-point voltage during discharge.

Q16: Capacity

A16:

Capacity (Ah, mAh) is the product of the discharge current (A, mA) and discharge time (h).
Note: Because manganese dry batteries and alkaline manganese batteries are often used for heavy-duty applications, the discharge time at a specific load is usually mentioned instead of the capacity.

Q17: Energy Density

A17:

Usable energy of a battery per unit volume or unit weight. The former is called volumetric energy density (Wh/l); the latter gravimetric energy density (Wh/kg).

Q18: Initial test

A18:

Test conducted within 2 months of the production month.

Q19: Storage

A19:

Store the battery under specified conditions.

Q20: Test after storage

A20:

Test conducted within 2 weeks after storage.

Q21: Aging

A21:

A finished or semi-finished battery is store under specified conditions for a specified period.

Q22: Expiry date

A22:

Expiration of guarantee period of a primary battery determined by each manufacturer conforming to the IEC. Because a secondary battery can be used over again by charging, it is unnecessary to show this.

Note: IEC (International Electrotechnical Commission) is a worldwide organization of standardization comprised of all national electrotechnical committees.

Q23: Active material

A23:

Electrode materials in a battery which cause an electrochemical reaction to generate electricity.

Ex) Battery Positive material Negative material
LR Manganese Dioxide Zinc
CR Manganese Dioxide Lithium

Q24: Electrolyte

A24:

Medium in a battery which causes ions to move to create an electrochemical reaction. Either water or non-aqueous solution is used as solvent. The latter is called non-aqueous electrolyte solution, either organic or inorganic.

Q25: Utilization factor

A25:

Ratio of usable capacity against theoretical capacity.

Q26: Leakage resistance

A26:

Enduring characteristics against leakage.

Q27: Short circuit current

A27:

Surges of current across the terminals of a battery when it is short-circuited.

Q28: Internal short circuit

A28:

Direct contact electrically between the positive electrode and negative electrode caused by damage to the separator or gasket, or the presence of a conductor piercing the separators. A battery will become completely exhausted before use.

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